A ruthenium(II) bipyridine complex containing a 4,5-diazafluorene moiety: Synthesis, characterization and its applications in transfer hydrogenation of ketones and dye sensitized solar cells

Autor:	Akın Baysal, Leyla Tatar Yıldırım, Saim Özkar, Yusuf Selim Ocak, Feyyaz Durap, Murat Aydemir
Rok vydání:	2015
Předmět:	Chemistry chemistry.chemical_element Transfer hydrogenation Photochemistry Catalysis Ruthenium Inorganic Chemistry Solvent Bipyridine chemistry.chemical_compound Dye-sensitized solar cell Hexafluorophosphate Polymer chemistry Materials Chemistry Moiety Physical and Theoretical Chemistry
Zdroj:	Polyhedron. 89:55-61
ISSN:	0277-5387
DOI:	10.1016/j.poly.2014.12.046
Popis:	The ruthenium(II) complex [Ru(bpy)2L](PF6)2, where bpy is 2,2′-bipyridine and L is 1,5-dihydro-2-H-cyclopenta[1,2-b:5,4-b′]dipyridine-2-one, was synthesized from the reaction of cis-Ru(bpy)2Cl2·2H2O with L, and isolated as the hexafluorophosphate salt. The structure of L was unequivocally elucidated by single-crystal X-ray diffraction analysis. The new ruthenium(II) complex was thoroughly characterized by 1H and 13C NMR spectroscopy, along with FTIR, UV–Vis and LC MS/MS Triple Quadrupole Mass spectroscopy and elemental analysis. The catalytic activity of [Ru(bpy)2L](PF6)2 was tested in the transfer hydrogenation of various ketones in 2-propanol as both the solvent and hydrogen donor. The usage of [Ru(bpy)2L](PF6)2 for the formation of a dye sensitized solar cell is also presented.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8a225ca81c8f58e961774148e1f65b06 https://doi.org/10.1016/j.poly.2014.12.046 Zobrazit plný text záznamu Full Text from ScienceDirect