Electrified microheterogeneous catalysis in low ionic strength media

Autor:	Debra R. Rolison, Joseph Z. Stemple
Rok vydání:	1993
Předmět:	Propene chemistry.chemical_compound Aqueous solution chemistry Inorganic chemistry Molecular Medicine Propylene oxide Partial oxidation Heterogeneous catalysis Electrocatalyst Molecular sieve Catalysis
Zdroj:	Journal of the Chemical Society, Chemical Communications. :25
ISSN:	0022-4936
DOI:	10.1039/c39930000025
Popis:	The ability to drive catalytic processes when dc voltages are applied to low ionic strength dispersions has been demonstrated for the selective partial oxidation of propene at 0 °C in an aqueous dispersion of PdII–CuII supported on Y zeolite where the primary partial oxidation product can be either acetone or propylene oxide depending on the nature of the dispersed solid; in the absence of the applied electrifying force no product forms and in the absence of the molecular catalyst no selective oxidation occurs.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8a002e40ebe8f758a72958d19865ab8d https://doi.org/10.1039/c39930000025 Zobrazit plný text záznamu