Autor:	M. I. Terekhova, E. S. Petrov, Yu. G. Noskov, T. E. Kron
Rok vydání:	2001
Předmět:	chemistry.chemical_element General Chemistry Photochemistry Medicinal chemistry Toluene Catalysis Computer Science Applications chemistry.chemical_compound chemistry Phenylacetylene Catalytic cycle Dibenzylideneacetone Modeling and Simulation Triphenylphosphine Carbon monoxide Palladium
Zdroj:	Kinetics and Catalysis. 42:182-188
ISSN:	0023-1584
DOI:	10.1023/a:1010453015217
Popis:	The reaction of phenylacetylene with CO and n-butanol in toluene (363 K) catalyzed by the Pd(dba)2/m(CF3COOH)/n(Ph3P) system (dba is dibenzylideneacetone; 2 ≤ m≤ 8; 10 ≤ n≤ 30) is studied. The initial rate of the main product (butyl 2-phenylpropenoate) buildup is found to depend on the pressure of CO and the concentrations of reactants and system components. The state of the catalyst under reaction conditions is studied in situby IR spectroscopy. A kinetic model is developed based on the experimental results. This model corresponds to the mechanism that resembles the hydride mechanism in the type of main intermediates in the catalytic cycle.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::89f5aef0c3c496a50d8c62df015ad327 https://doi.org/10.1023/a:1010453015217 Zobrazit plný text záznamu Full text from SpringerLink