Recherches dans la série des cyclitols, XL. Préparation de cyclopentane-triols et de cyclopentène-triols et -diols

Autor:	F. G. Cocu, G. Wolczunowicz, Th. Posternak
Rok vydání:	1970
Předmět:	Allylic rearrangement Bromine Chemistry Dimethyl sulfoxide Sodium Organic Chemistry chemistry.chemical_element Biochemistry Catalysis Inorganic Chemistry chemistry.chemical_compound Drug Discovery Halogen Organic chemistry Cyclopentene Physical and Theoretical Chemistry
Zdroj:	Helvetica Chimica Acta. 53:2275-2288
ISSN:	0018-019X
DOI:	10.1002/hlca.19700530842
Popis:	Two as yet unknown cyclopentene-triols have been prepared. The replacement of the halogen of cyclopentene derivatives brominated in the allylic position has been investigated. In the presence of dimethyl sulfoxide and sodium hydrogen carbonate, the bromine of some of the above mentioned allylic derivatives or the tosyloxy group of a dibenzoyloxy-monotosyloxy-cyclopentane derivative is replaced by a hydroxyl group without formation of any keto compound. The mechanism of action of the substitution agents is discussed.
Databáze:	OpenAIRE
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