Kristallstrukturen von isopropyl- und trimethylsilylmethylen-substituierten chloro-hydroxo-tetraorganyl-distannoxanen

Autor:	Edmund Friedrichs, Iris Bung, Andrea Jansen, Heinrich Puff
Rok vydání:	1983
Předmět:	Stereochemistry Dimer Organic Chemistry Chlorine atom chemistry.chemical_element Crystal structure Biochemistry Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound chemistry X-ray crystallography Materials Chemistry Physical and Theoretical Chemistry Tin
Zdroj:	Journal of Organometallic Chemistry. 254:23-32
ISSN:	0022-328X
DOI:	10.1016/0022-328x(83)85113-4
Popis:	According to the results of the X-ray analysis, 1-chloro-3-hydroxo-tetra-isopropyl-distannoxane and 1-chloro-3-hydroxo-tetra-(trimethylsilylmethylene)-distannoxane are dimeric and show a “ladder-type” structure analogous to the 1,3-dichloro-and 1,3-dihydroxo derivatives. In contrast to the terminal chlorine atoms, the hydroxyl groups form strong asymmetric bridges between two tin atoms; the two compounds differ slightly in the asymmetry of these bridges.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::89e21a8077d3d2d348636b6b318e5429 https://doi.org/10.1016/0022-328x(83)85113-4 Zobrazit plný text záznamu