Nucleophilic addition reactions of 1,5-anhydro-4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-d-erythro-hex-2-enitol and its 5a-carba derivative

Autor:	Takeshi Tamura, Shinji Ito, Kiohisa Tokuda, Akinori Seta, Yaeko Konda, Tohru Sakakibara
Rok vydání:	1995
Předmět:	chemistry.chemical_classification Nucleophilic addition Stereochemistry Alkene Organic Chemistry General Medicine Biochemistry Nucleophilic abstraction Analytical Chemistry chemistry Nucleophile Nitro Moiety Stereoselectivity Acid hydrolysis
Zdroj:	Carbohydrate Research. 267:217-226
ISSN:	0008-6215
DOI:	10.1016/0008-6215(94)00304-x
Popis:	Reactions of the title compounds with several nucelophiles suggested that the ring oxygen atom (O-5) accelerated the reactivity of the nitro alkene moiety, but scarcely affected the stereoselectivity of the nucleophilic attack.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::89bb51747b3a14d06c5a6065355d75e4 https://doi.org/10.1016/0008-6215(94)00304-x Zobrazit plný text záznamu Full Text from ScienceDirect