Lipases immobilized on the modified polyporous magnetic cellulose support as an efficient and recyclable catalyst for biodiesel production from Yellow horn seed oil
| Autor: | Wang Xiqing, Hong Li, Yu-Jie Fu, Ya-Wei Zhu, Li Tianfeng, Hua-Xia Zhang, Liu Tianshu |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Biodiesel
060102 archaeology biology Renewable Energy Sustainability and the Environment 020209 energy Triacylglycerol lipase food and beverages 06 humanities and the arts 02 engineering and technology Transesterification biology.organism_classification Grafting Catalysis chemistry.chemical_compound chemistry Biodiesel production 0202 electrical engineering electronic engineering information engineering 0601 history and archaeology Candida antarctica Cellulose Nuclear chemistry |
| Zdroj: | Renewable Energy. 145:1246-1254 |
| ISSN: | 0960-1481 |
| DOI: | 10.1016/j.renene.2019.06.031 |
| Popis: | In the present study, modified polyporous magnetic cellulose beads (PMCBs) were synthesized by several organic amines (EDA, DETA, TETA and AST) grafting PMCBs and then utilized as a new kind of support to immobilize Candida antarctica lipase B (CALB) for biodiesel production. The immobilized lipase catalysts based on PMCBs were characterized by Fourier transform infrared and scanning electron microscopy. The results showed that PMCBs-DETA was a more suitable immobilization support and the catalytic activity of immobilized lipases could reach 1.0 U/mg. Then the synthesized catalyst of CALB-PMCBs-DETA was used to produce biodiesel from Yellow horn seed oil via transesterification reaction. A high biodiesel yield (92.3%) was obtained under the optimal reaction conditions and the main compositions of the prepared biodiesel were tested by GC-MS. Moreover, the catalyst of CALB-PMCBs-DETA could be removed easily by a magnet and recycled at least 5 times. As a new kind of support, the modified PMCBs could be a promising alternative for the carriers of immobilizing enzymes used for the green and efficient production of biodiesel. |
| Databáze: | OpenAIRE |
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