Template synthesis and characterization of mononuclear (La, Yb), homobinuclear (Ce, Eu) and heterobinuclear (La/Sn) complexes with an acyclic lipophylic schiff base derived from 2,6-diformyl-4-methylphenol
| Autor: | Gaye Mohamed, Sall Abdou Salam, Vidali Maurizio, Umberto Russo, Sarr Oumar |
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| Rok vydání: | 1995 |
| Předmět: |
Schiff base
Chemistry Stereochemistry Infrared chemistry.chemical_element Template synthesis Inorganic Chemistry Metal chemistry.chemical_compound Crystallography visual_art Mössbauer spectroscopy Octahedral molecular geometry Atom Materials Chemistry visual_art.visual_art_medium Physical and Theoretical Chemistry Tin |
| Zdroj: | Polyhedron. 14:655-661 |
| ISSN: | 0277-5387 |
| Popis: | New lipophylic compounds LaL(NO3)·5H2O, YbL(NO3)·2H2O, Ce2L (NO3)2(OH)2·6H2O, Eu2L(NO3)2(OH)2·2H2O·2EtOH and LaSnMe2Cl2L(NO3)·5H2O [L C38H55N3O4] have been synthesized by a template condensation and characterized by using infrared and Mossbauer spectroscopies. In the homopolynuclear compounds, the two compartments in close proximity are both occupied, while for the La/Sn compound the SnMe2Cl2 was bonded by oxygen atoms out of these compartments; the Mossbauer parameters seemed to indicate a severely distorted trans octahedral geometry around the tin atom. For the mononuclear complexes, the metal La or Yb was encapsulated in the inner N3O4 compartment. |
| Databáze: | OpenAIRE |
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