Sterisch gehinderte Alkene, VII Röntgenstrukturanalyse und Reaktionen des Tetrakis-(2-formyl-2-propyl)ethens

Autor:	Jürgen Kopf, Adolf Krebs, Liane Tikwe, Wolf-Ulrich Dr Nickel
Rok vydání:	1985
Předmět:	chemistry.chemical_classification Allylic rearrangement Chemistry Stereochemistry Organic Chemistry Dihedral angle Biochemistry Bond length Crystallography Molecular geometry Hydrocarbon Drug Discovery X-ray crystallography Molecule Aliphatic compound
Zdroj:	Tetrahedron Letters. 26:1639-1642
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)98572-1
Popis:	The tetraaldehyde {=1} was synthesized by ozonation of the triene {=3}. The C=C-bond in {=1} is twisted by 28.6° and the CC-bond and the allylic bond lengths are significantly elongated to 135.7 and 155.5–159.7 pm, resp.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8959cc017a19b8426c6e45e736503726 https://doi.org/10.1016/s0040-4039(00)98572-1 Zobrazit plný text záznamu