Photoreduction of CO to Methanol. The Photolysis of Aqueous Solutions of [Os(NH3)5(CO)]2+

Autor:	Arnd Vogler, Horst Kunkely
Rok vydání:	2013
Předmět:	chemistry.chemical_compound Aqueous solution Chemistry Inorganic chemistry Photodissociation General Chemistry Methanol Photochemistry Artificial photosynthesis
Zdroj:	Zeitschrift für Naturforschung B. 68:1371-1374
ISSN:	1865-7117 0932-0776
DOI:	10.5560/znb.2013-3197
Popis:	The carbonyl complex [OsII(NH3)5(CO)]2+ undergoes a photolysis in aqueous solution which yields [OsVI(NH3)4N]3+ (Φ=10-3 at λirr =255 nm) and methanol. This photoreduction of CO to CH3OH represents a novel type of photoreactivity of metal carbonyl complexes and could be utilized for an artificial photosynthesis
Databáze:	OpenAIRE
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