Rubber particle agglomeration phenomena in acrylonitrile-butadiene-styrene (ABS) polymers. I. Structure-property relationships study on rubber particle agglomeration and molded surface appearance

Autor: R. L. Nemeth, M. C. O. Chang
Rok vydání: 1996
Předmět:
Zdroj: Journal of Applied Polymer Science. 61:1003-1010
ISSN: 1097-4628
0021-8995
Popis: The effects of molecular structures of ABS fabricated under a severe molding condition on rubber particle agglomeration and molded specular gloss were studied. An agglomeration index (NP) obtained by measuring particle size was used to determine the degree of rubber particle agglomeration. It was found that as graft level decreased, agglomeration increased. The rubber particle agglomeration also increased when graft molecular weight was increased. Lowering the particle size also led to a higher degree of agglomeration. Furthermore, increasing the compositional acrylonitrile mismatch between the grafted and matrix styrene-acrylonitrile copolymers increased the rubber particle agglomeration. Molecular structures that increased rubber particle agglomeration decreased the molded gloss. © 1996 John Wiley & Sons, Inc.
Databáze: OpenAIRE