Broadband Dielectric Spectroscopy of PSN-Rich PMN-PSN Ceramics

Autor: Robertas Grigalaitis, Juras Banys, Vismants Zauls, A. Brilingas, Karlis Bormanis, Andris Sternberg
Rok vydání: 2008
Předmět:
Zdroj: Ferroelectrics. 369:190-197
ISSN: 1563-5112
0015-0193
DOI: 10.1080/08838150802378145
Popis: The broadband dielectric permittivity of ordered 0.1PMN-0.9PSN and disordered 0.2PMN-0.8PSN ceramics was investigated. The anomaly of dielectric permittivity is clearly seen in the region of 370 K for 0.1 PMN-0.9 PSN at all frequencies. 0.2 PMN-0.8 PSN shows relaxor behaviour with huge frequency dispersion below 350 K. Calculated distribution of relaxation times shows noticeable influence of polar nano regions to the total dielectric spectrum below 320 K with the longest relaxation times edge diverging according to the Vogel-Fulcher law. In 0.1 PMN-0.9 PSN two a little overlapped peaks present in the distribution of relaxation times, influenced by displacive lead motions at high frequencies and possible conductivity phenomena at low frequencies.
Databáze: OpenAIRE