Methane conversion to higher value-added product and energy co-generation using anodes OF PdCu/C in a solid electrolyte reactor: alkaline fuel cell type monitored by differential mass spectroscopy

Autor:	Araceli Jardim da Silva, A. Oliveira Neto, Andrezza S. Ramos, Monique C.L. Santos, R. F. B. de Souza, C.M. Godoi, T. L. Tagomori
Rok vydání:	2020
Předmět:	Alkaline fuel cell 010405 organic chemistry Chemistry Methyl formate Inorganic chemistry General Chemistry Electrolyte 010402 general chemistry 01 natural sciences Methane 0104 chemical sciences Potassium formate chemistry.chemical_compound Dimethyl ether Partial oxidation Methanol
Zdroj:	Research on Chemical Intermediates. 47:743-757
ISSN:	1568-5675 0922-6168
DOI:	10.1007/s11164-020-04296-4
Popis:	PdxCuy/C catalysts combinations were employed to CH4 partial oxidation in mild condition using a solid electrolyte reactor—alkaline fuel cell type. The differential mass spectroscopy on line method was used to monitor the oxidation products obtained as methanol, dimethyl ether, methyl formate and potassium formate. It was observed that as the electrical potential of the reactor increases, the generation of products decreases. The best results for conversion of methane into methanol and energy co-generation was obtained from Pd90Cu10/C and Pd50Cu50/C due to better H2O activation effects and adsorption site for CH4 oxidation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::892fbeb3e15f491a9c837773665b50d4 https://doi.org/10.1007/s11164-020-04296-4 Zobrazit plný text záznamu Full text from SpringerLink