Synthesis and characterization of triosmium-bis[60]fullerene and bis(metal cluster)[60]fullerene compounds
| Autor: | Bo Keun Park |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Fullerene
Chemistry General Chemistry Dppm ligand 010402 general chemistry Condensed Matter Physics Photochemistry Electrochemistry 01 natural sciences 0104 chemical sciences Characterization (materials science) Metal visual_art Polymer chemistry visual_art.visual_art_medium Cluster (physics) General Materials Science Cyclic voltammetry |
| Zdroj: | Molecular Crystals and Liquid Crystals. 636:155-158 |
| ISSN: | 1563-5287 1542-1406 |
| Popis: | Triosmium-bis[60]fullerene compound containing dppm ligand, Os3(CO)7(dppm)(C60)2 (1), was synthesized by reaction of Os3(CO)9(μ3-η2:η2:η2-C60) and dppm ligand with Me3NO/MeCN. Reaction of Os3(CO)7(1,2-dppm)(μ3-η2:η2:η2-C60) and Re3(μ-H)3(CO)11(NCMe) produced bis(metal-cluster)[60]fullerene compound, [Os3(CO)7(1,2-dppm)](μ3-η2:η2:η2-C60)[Re3(μ-H)3(CO)9] (2). Compounds 1 and 2 were characterized by IR, NMR (1H and 31P), and Mass. Electrochemical property of 1 was confirmed by cyclic voltammetry (CV). |
| Databáze: | OpenAIRE |
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