Preparation of lithium ion conducting solid electrolyte of NASICON-type Li1+xAlxTi2−x(PO4)3 (x = 0.3) obtained by using the mechanochemical method and its application as surface modification materials of LiCoO2 cathode for lithium cell
| Autor: | Yohei Shindo, Nobukiyo Ito, Hiroyuki Awano, Hideyuki Morimoto, Kiyotaka Ishikawa, Junpei Terashima, Shin-ichi Tobishima, Shinji Nakanishi |
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| Rok vydání: | 2013 |
| Předmět: |
Materials science
Lithium vanadium phosphate battery Renewable Energy Sustainability and the Environment Inorganic chemistry Energy Engineering and Power Technology chemistry.chemical_element Electrolyte Conductivity Cathode Amorphous solid law.invention chemistry law Fast ion conductor Lithium Electrical and Electronic Engineering Physical and Theoretical Chemistry Solid solution |
| Zdroj: | Journal of Power Sources. 240:636-643 |
| ISSN: | 0378-7753 |
| DOI: | 10.1016/j.jpowsour.2013.05.039 |
| Popis: | Amorphous a-LATP (x = 0.3) fine powder with the composition of Li1+xAlxTi2−x(PO4)3 in Li2O–Al2O3–TiO2–P2O5 system was prepared directly from a mixture of Li2O, γ-Al2O3, TiO2, and P2O5 as starting materials, by using a mechanical milling (MM) technique at room temperature. A NASICON-type Li1+xAlxTi2−x(PO4)3 (x = 0.3) (c-LATP (x = 0.3)) solid solution was obtained by the heat treatment of mechanochemically prepared amorphous a-LATP (x = 0.3) material. The sintered c-LATP (x = 0.3) pellet showed high lithium ion conductivity of the order of 10−4 S cm−1 at room temperature and activation energy of about 35 kJ mol−1. The high-conducting lithium ion c-LATP (x = 0.3) solid electrolyte fine powders were investigated as surface modification materials of LiCoO2 cathode in lithium cells using nonaqueous electrolyte solutions. The c-LATP (x = 0.3)-modified LiCoO2 electrodes exhibited high capacity (ca. 180 mAh g−1) and good cycle performance with a high charge cut-off potential of 4.5 V (vs. Li/Li+) in lithium cell. The increase in the electrode/electrolyte interfacial resistance for the LiCoO2 electrode modified with c-LATP (x = 0.3) fine powder was inhibited. |
| Databáze: | OpenAIRE |
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