Adsorption of P(St-co-DMHB-co-BA) n+·Br n - nanoscale particles onto cotton fiber surfaces: A study by conductometric titration

Autor:	Xiu-Ming Liu, Kuan-Jun Fang, Dong-Qin He
Rok vydání:	2015
Předmět:	Materials science Polymers and Plastics Conductometry General Chemical Engineering Analytical chemistry Molar conductivity Langmuir adsorption model General Chemistry Conductivity symbols.namesake Adsorption Polymer chemistry Monolayer symbols Fiber Dispersion (chemistry)
Zdroj:	Fibers and Polymers. 16:1237-1242
ISSN:	1875-0052 1229-9197
DOI:	10.1007/s12221-015-1237-9
Popis:	A more sensitive and accurate method for measuring very low concentration of cationic copolymer nanospheres is established by measuring the conductivity of cationic nanosphere dispersion. The effect of the nanosphere concentration on the conductivity was investigated during the adsorption process. The results indicate that the relationship between the concentration of nanospheres and bromide ions is coincidence with linear relation. At very low nanosphere concentrations, the conductivity increases with increasing the nanosphere concentration, exhibiting a linear relationship. However, the limiting molar conductivity of nanosphere decreases with increasing nanosphere concentration. The obtained adsorption data were fitted to the Langmuir adsorption isotherm. The SEM images show that the nanospheres form a uniform monolayer on cotton fiber surfaces. The saturated amount of the nanospheres on the cotton fibers is 63.49 mg/g.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::88b83e226a588880911b8bb8f97ebe3f https://doi.org/10.1007/s12221-015-1237-9 Zobrazit plný text záznamu Full text from SpringerLink