Electroreduction of tetra-coordinate phosphonium derivatives; one-pot transformation of triphenylphosphine oxide into triphenylphosphine

Autor:	Hideo Tanaka, Hiromu Kawakubo, Manabu Kuroboshi, Tomotake Yano, Shogo Kamenoue
Rok vydání:	2011
Předmět:	Triphenylphosphine dichloride Organic Chemistry Inorganic chemistry chemistry.chemical_element Biochemistry chemistry.chemical_compound Oxalyl chloride chemistry Drug Discovery Polymer chemistry Phosphonium Lewis acids and bases Triphenylphosphine Platinum Acetonitrile Triphenylphosphine oxide
Zdroj:	Tetrahedron. 67:5825-5831
ISSN:	0040-4020
DOI:	10.1016/j.tet.2011.05.044
Popis:	Electroreduction of triphenylphosphine dichloride in acetonitrile was performed successfully in an undivided cell fitted with an aluminium sacrificial anode and a platinum cathode, wherein Al3+, which was electrogenerated at the anode would react as a Lewis acid with triphenylphosphine dichloride to afford tetra-coordinate chlorotriphenylphosphonium species and subsequent two-electron reduction at the cathode would give triphenylphosphine. One-pot transformation of triphenylphosphine oxide to triphenylphosphine was achieved successfully by the treatment of triphenylphosphine oxide with oxalyl chloride and subsequent electroreduction. In a similar manner, some tetra-coordinate triphenylphosphonium species derived from triphenylphosphine oxide were reduced electrochemically to triphenylphosphine in moderate yields.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::88b0cc43131574b955367c340d003216 https://doi.org/10.1016/j.tet.2011.05.044 Zobrazit plný text záznamu Full Text from ScienceDirect