Electrochemical synthesis of tris(2-chloroethyl) phosphate

Autor: A. P. Tomilov, V. V. Turygin, M. Yu. Berezkin
Rok vydání: 2015
Předmět:
Zdroj: Russian Journal of Electrochemistry. 51:1086-1091
ISSN: 1608-3342
1023-1935
DOI: 10.1134/s1023193515110026
Popis: Process of preparation of tris(2-chloroethyl) phosphate, a neutral ester of ethylene chlorohydrin and phosphoric acid, by direct electrochemical synthesis from elemental phosphorus and ethylene chlorohydrin in a diaphragmless electrolyzer was studied. Solubility of white phosphorus in tris(2-chloroethyl) phosphate was studied. The formation of tris(2-chloroethyl) phosphate from white and red phosphorus was found to proceed in close yields.
Databáze: OpenAIRE