Structure and reactivity of (Dibenzo[b,e]fulvalene)Mo2(CO)6

Autor:	Robert C. Kerber, Brian R. Waldbaum
Rok vydání:	1996
Předmět:	Fulvalene Organic Chemistry chemistry.chemical_element Photochemistry Biochemistry Medicinal chemistry Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Molybdenum Materials Chemistry Reactivity (chemistry) Physical and Theoretical Chemistry Bimetallic strip
Zdroj:	Journal of Organometallic Chemistry. 513:277-280
ISSN:	0022-328X
DOI:	10.1016/0022-328x(95)06099-i
Popis:	The title compound 1 was prepared by a one pot double-deprotonation, migration, and oxidation sequence staring with ( μ , η 6 : η 6 -2,2′-biindenyl)Mo 2 (CO) 6 ( 2 ). An X-ray structure was determined, and the relevant structural features are compared with analogous fulvalene and dibenzo[a,d]fulvalene complexes. The reactions of 1 with 4-octyne and P(CH 3 ) 3 are described. Compound 1 is a more effective catalyst in the Kharasch reaction than other bimetallic molybdenum complexes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::889a5195fbe0f379a30255b8c8b8b752 https://doi.org/10.1016/0022-328x(95)06099-i Zobrazit plný text záznamu Full Text from ScienceDirect