Platinum(II) complexes of 2-alkoxy-dibenzo[c.e][1,2]oxaphosphorines

Autor:	Andrea Kerényi, György Keglevich, Beatrix Mayer, Krisztina Ludányi, Tamás Körtvélyesi
Rok vydání:	2008
Předmět:	Quantum chemical Chemistry Energetics Metals and Alloys chemistry.chemical_element Boranes Medicinal chemistry Catalysis Inorganic Chemistry chemistry.chemical_compound Materials Chemistry Alkoxy group Organic chemistry Platinum Organometallic chemistry Cis–trans isomerism
Zdroj:	Transition Metal Chemistry. 33:505-510
ISSN:	1572-901X 0340-4285
DOI:	10.1007/s11243-008-9072-0
Popis:	2-Alkoxy-dibenzo[c.e][1,2]oxaphosphorines were prepared by the reaction of chloro-dibenzooxaphosphorine with alcohols and were converted to the cyclic phosphonates by oxidation and to the corresponding phosphonous boranes by reaction with borane-dimethylsulfide. Interaction of the alkoxy-dibenzooxaphosphorines with dichlorodibenzonitrileplatinum led to bis(dibenzooxaphosphorino)dichloroplatinum complexes exhibiting the P-ligands in the cis disposition. Relative energetics for the prepared cis and the theoretically possible trans isomers of the complexes along with their stereostructures were investigated by quantum chemical calculations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8861efac9de4feae95333c40212f6444 https://doi.org/10.1007/s11243-008-9072-0 Zobrazit plný text záznamu Full text from SpringerLink