A novel synthesis of 2,3-dihydro-7(1H)-indolizinones
Autor: | David Gravestock, Ian G. Peirson |
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Rok vydání: | 2000 |
Předmět: | |
Zdroj: | Tetrahedron Letters. 41:3497-3500 |
ISSN: | 0040-4039 |
Popis: | Intramolecular coupling reactions of enynes 2-[1-(2-propynyl)tetrahydro-2H-pyrrol-2-ylidene]acetonitrile (10) and ethyl 2-[1-(2-propynyl)tetrahydro-2H-pyrrol-2-ylidene]acetate (11), using 9-BBN, catecholborane and alkaline silver nitrate, afforded the 2,3-dihydro-7(1H)-indolizinones, 7-oxo-1,2,3,7-tetrahydro-8-indolizinecarbonitrile (5) and ethyl 7-oxo-1,2,3,7-tetrahydro-8-indolizinecarboxylate (6), respectively. |
Databáze: | OpenAIRE |
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