Oxygen Non-Stoichiometry and Point Defect Equilibria in (La1/6Pr1/6Nd1/6Gd1/6Ba1/6Sr1/6)MnO3- δ
| Autor: | Sean R Bishop, Dawei Zhang, Cijie Liu, Wei Li, Perla A Salinas, Andrew I Smith, Eric N Coker, Héctor A De Santiago, Xingbo Liu, Anthony H McDaniel, Jian Luo |
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| Rok vydání: | 2023 |
| Předmět: | |
| Zdroj: | ECS Transactions. 111:1135-1138 |
| ISSN: | 1938-6737 1938-5862 |
| Popis: | In this work, the A-site of the common SOFC cathode La0.8Sr0.2MnO3-δ (LSM) is modified with additional lanthanide and alkali elements, resulting in the composition (La1/6Pr1/6Nd1/6Gd1/6Ba1/6Sr1/6)MnO3- δ. We show that the amount of oxygen released during reduction measured by thermo-gravimetric analysis is significantly greater for this “high entropy” perovskite oxide (HEPO) in comparison with La2/3Sr1/3MnO3-δ, the latter having the same amount of total acceptor dopant and with a similar average A-site radius. The origins of enhanced reduction will be discussed. |
| Databáze: | OpenAIRE |
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