Electrodeposition NiMoSe ternary nanoshperes on nickel foam as bifunctional electrocatalyst for urea electrolysis and hydrogen evolution reaction
| Autor: | Wenlu Zeng, Ying Zhang, Yongli Jiao, Haitao Wang, Xin Jiao |
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| Rok vydání: | 2021 |
| Předmět: |
Electrolysis
Materials science Renewable Energy Sustainability and the Environment Energy Engineering and Power Technology chemistry.chemical_element Condensed Matter Physics Electrochemistry Electrocatalyst Cathode Anode law.invention Nickel Fuel Technology Chemical engineering chemistry law Electrode Ternary operation |
| Zdroj: | International Journal of Hydrogen Energy. 46:37792-37801 |
| ISSN: | 0360-3199 |
| DOI: | 10.1016/j.ijhydene.2021.09.050 |
| Popis: | Electrodeposition provides a simple but effective way to prepare advanced electrode for the application in electrochemical field. In this work, NiMoSe ternary nanospheres were deposited on nickel foam (NiMoSe/NF) by one-step electrodeposition. The morphology, phase and chemical composition of the electrode was characterized by using SEM, TEM, XRD and XPS. The electrode exhibited excellent performance for both urea oxidation reaction (UOR) and hydrogen evolution reaction (HER). It only required 1.39 V and 81 mV (vs. RHE) to deliver a current density of 10 mA/cm2 for UOR and HER, respectively. The electrolyzer constructed with NiMoSe/NF as both anode and cathode could deliver a current density of 10 mA/cm2 at a driving potential of 1.44 V. The stability test showed that the electrode had good durability as electrode for both UOR and HER. Considering the easiness, simplicity and low cost, the NiMoSe/NF electrode could find wide application in urea electrolysis. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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