Charge-transporting 3,4-ethylenedioxythiophene-based hydrazone monomers and oligomers
| Autor: | Vygintas Jankauskas, A. Michaleviciute, Jolita Ostrauskaite, Juozas V. Grazulevicius, Ramunas Lygaitis, Nerijus Pedišius, Egle Andrikaityte |
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| Rok vydání: | 2013 |
| Předmět: |
chemistry.chemical_classification
Materials science Polymers and Plastics Cationic polymerization Hydrazone General Chemistry Condensed Matter Physics Photochemistry Electrochemistry chemistry.chemical_compound Monomer chemistry Ionization visual_art Polymer chemistry Materials Chemistry visual_art.visual_art_medium Polycarbonate Boron trifluoride Solid solution |
| Zdroj: | Polymer Bulletin. 70:1519-1529 |
| ISSN: | 1436-2449 0170-0839 |
| DOI: | 10.1007/s00289-012-0904-x |
| Popis: | 3,4-Ethylenedioxythiophene-based hydrazones, containing reactive functional groups were synthesized and their optical, thermal, photophysical and electrochemical properties were studied. The monomers were subjected to cationic polymerization using boron trifluoride etherate as an initiator. The ionization potentials of the films of the hydrazones, measured by the electron photoemission technique, range from 5.53 to 5.62 eV. Room temperature time-of-flight hole mobilities in the solid solutions of 3,4-ethylenedioxythiophene hydrazone monomers in bisphenol-Z polycarbonate exceed 10−5 cm2 V−1 s−1 at high applied electric fields. |
| Databáze: | OpenAIRE |
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