Crossed‐beam (full collision) versus van der Waals (half collision) studies. Application to the determination of the D00(Ca...HCl)

Autor: A. González Ureña, M. Garay, M. Menéndez, J. E. Verdasco
Rok vydání: 1994
Předmět:
Zdroj: The Journal of Chemical Physics. 100:756-757
ISSN: 1089-7690
0021-9606
DOI: 10.1063/1.466895
Popis: The dissociation energy of the van der Waals molecule Ca...HCl in its ground state, D00(Ca...HCl), has been determined using energy balance arguments. By combining collisional information from the Ca(3P)+HCl→CaCl(A 2Π)+H reaction with spectroscopic information from the Ca...HCl+hν→CaCl(A 2Π)+H reaction we found D00(Ca...HCl)≤150 meV.
Databáze: OpenAIRE