Crossed‐beam (full collision) versus van der Waals (half collision) studies. Application to the determination of the D00(Ca...HCl)
Autor: | A. González Ureña, M. Garay, M. Menéndez, J. E. Verdasco |
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Rok vydání: | 1994 |
Předmět: |
Chemistry
Van der Waals molecule Van der Waals strain General Physics and Astronomy Chemical reaction Bond-dissociation energy symbols.namesake symbols Van der Waals radius Physics::Chemical Physics Physical and Theoretical Chemistry van der Waals force Atomic physics Nuclear Experiment Ground state Astrophysics::Galaxy Astrophysics Beam (structure) |
Zdroj: | The Journal of Chemical Physics. 100:756-757 |
ISSN: | 1089-7690 0021-9606 |
DOI: | 10.1063/1.466895 |
Popis: | The dissociation energy of the van der Waals molecule Ca...HCl in its ground state, D00(Ca...HCl), has been determined using energy balance arguments. By combining collisional information from the Ca(3P)+HCl→CaCl(A 2Π)+H reaction with spectroscopic information from the Ca...HCl+hν→CaCl(A 2Π)+H reaction we found D00(Ca...HCl)≤150 meV. |
Databáze: | OpenAIRE |
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