Solution-based determination of trace elements in biogenic carbonates: comparison of two sample introduction systems for use in flow injection ICPMS analysis

Autor:	Magali Rompais, Ian M. Davies, Craig D. Robinson, Sandhya Devalla
Rok vydání:	2009
Předmět:	Detection limit Elemental composition Chemistry Flow (psychology) Population structure Analytical chemistry Analytical Chemistry medicine.anatomical_structure Certified reference materials medicine Fish Two sample Spectroscopy Otolith
Zdroj:	Journal of Analytical Atomic Spectrometry. 24:939
ISSN:	1364-5544 0267-9477
Popis:	The elemental composition of fish ear stones (otoliths) is used to inform upon environmental conditions, fish migrations, population structure, and nursery areas. We compared two nebuliser/spray chamber configurations for determining concentrations of Mg, Ca, Mn, Cu, Zn Rb, Sr, Ba, La and Pb in acidic otolith digests using flow injection ICPMS with: (1) cross-flow nebuliser/Scott spray chamber and (2) microconcentric nebuliser/Peltier-cooled cyclonic spray chamber. For most elements, both configurations had acceptable accuracy (within certified or indicative ranges) and precision (
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::882b9e35145aa7021baa1d32d743263e https://doi.org/10.1039/b904170b Zobrazit plný text záznamu