Synthesis of triphenylene derivatives by Pd-catalyzed Suzuki coupling/intramolecular C H activation between arylboronic acids and dibromobiphenyls

Autor:	Jingxuan Tu, Feng Xu, Gaoqiang Li, Xiaoqian Zhao
Rok vydání:	2019
Předmět:	010405 organic chemistry Organic Chemistry Regioselectivity Triphenylene 010402 general chemistry 01 natural sciences Biochemistry Combinatorial chemistry 0104 chemical sciences Catalysis Coupling (electronics) chemistry.chemical_compound chemistry Suzuki reaction Intramolecular force Drug Discovery
Zdroj:	Tetrahedron Letters. 60:44-47
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2018.11.052
Popis:	An efficient and regioselective synthesis of functionalized triphenylenes via palladium-catalyzed Suzuki-Miyaura coupling and subsequent intramolecular C H activation between arylboronic acids and dibromobiphenyls was developed. This methodology showed excellent atomic economy and regiospecificity as well as synthetic feasibility of unsymmetrical triphenylenes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::882705ca4085a04200884650d1438325 https://doi.org/10.1016/j.tetlet.2018.11.052 Zobrazit plný text záznamu Full Text from ScienceDirect