Determination of Pentachlorophenol (PCP) in Samples of the Environmental Specimen Bank Using Isotope Dilution
| Autor: | S. Amberg, Karl-Werner Schramm, Antonius Kettrup, Dieter Martens, K. Oxynos, V. Prachar |
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| Rok vydání: | 1997 |
| Předmět: |
Chromatography
Chemistry Health Toxicology and Mutagenesis Extraction (chemistry) Public Health Environmental and Occupational Health Soil Science Isotope dilution Mass spectrometry Pollution Analytical Chemistry law.invention Pentachlorophenol Steam distillation Acetic anhydride chemistry.chemical_compound law Environmental chemistry Environmental Chemistry Gas chromatography Derivatization Waste Management and Disposal Water Science and Technology |
| Zdroj: | International Journal of Environmental Analytical Chemistry. 68:415-427 |
| ISSN: | 1029-0397 0306-7319 |
| DOI: | 10.1080/03067319708030844 |
| Popis: | Within the program of the Environmental Specimen Bank a quick and efficient method for determination of pentachlorophenol (PCP) in various environmental matrices has been developed. The method includes alkaline hydrolysis of bound PCP, acidification, simultaneous steam distillation and extraction in one glass apparatus. After clean-up and derivatization with acetic anhydride the samples were analyzed by gas chromatography/mass spectrometry. Concentrations were calculated using 13C-labeled PCP as the internal standard. Validation was carried out with various environmental samples (soil, fish, conifer needles, kale). The method can be used for various biological samples without any modification. The extracts are free of matrix components (lipids, chloropyll, terpenes, etc.) and other contaminants, which results in clear chromatograms with few peaks; therefore, correct integration is facilitated. Although the recoveries of PCP are in the range of 50–90%, due to losses during the several method steps... |
| Databáze: | OpenAIRE |
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