Popis: |
In the radiolysis of aqueous solutions of indole, indole-3-acetic acid, indole-3-propionic acid, 1-naphthylacetic acid and phenylacetic acid, the absolute rate constants of their reactions with H and OH have been determined by competition kinetics using 2-propanol as the competitor. Hydrated electron reaction rate constants have been determined for indoie, indole-3-acetic acid and indole-3-propionic acid at pH = 11 using the decay of the hydrated electron generated by the photolysis of OH− in a H2 saturated solution. The rate constants have been compared with literature values for other indole derivatives. |