Palladium(II) and platinum(II) complexes containing dimesyloxy-substituted chiral diamines
| Autor: | Pak-Hing Leung, Chin-Chin Lim, K. F. Mok, Keng-Yeow Sim |
|---|---|
| Rok vydání: | 1997 |
| Předmět: |
chemistry.chemical_classification
Ligand Organic Chemistry chemistry.chemical_element Salt (chemistry) Catalysis Inorganic Chemistry Metal chemistry.chemical_compound chemistry visual_art Diamine Polymer chemistry visual_art.visual_art_medium Organic chemistry Physical and Theoretical Chemistry Platinum Palladium |
| Zdroj: | Tetrahedron: Asymmetry. 8:2045-2050 |
| ISSN: | 0957-4166 |
| DOI: | 10.1016/s0957-4166(97)00179-1 |
| Popis: | The physically stable but chemically reactive square-planar complex (+)-[(dichloro){(S,S)-1,4-dimesyloxy-2,3-butanediamine} palladium(II)] and its platinum(II) analogue have been prepared from the reactions between the dihydrochloride salt of the diamine and K2MCl4 (where M=Pd, Pt) in water. The palladium complex has been analysed by X-ray crystallography. In contrast to their metal complexes, the free diamine ligand and its dihydrochloride salt are unstable and cannot be isolated. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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