A film-based fluorescent device for vapor phase detection of acetone and related peroxide explosives
| Autor: | Haonan Peng, Nannan Ding, Yu Fang, Yanyu Qi, Congdi Shang, Taihong Liu, Xingmao Chang, Wenjun Xu |
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| Rok vydání: | 2019 |
| Předmět: |
Detection limit
Materials science Fluorophore Solvation 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences Fluorescence Peroxide 0104 chemical sciences chemistry.chemical_compound chemistry Materials Chemistry Acetone General Materials Science Solvent effects 0210 nano-technology Perylene |
| Zdroj: | Materials Chemistry Frontiers. 3:1218-1224 |
| ISSN: | 2052-1537 |
| DOI: | 10.1039/c9qm00095j |
| Popis: | On site, sensitive and selective detection of acetone vapor at room temperature is of great importance for health, and in particular for in air detection of triacetone triperoxide (TATP) and diacetone diperoxide (DADP), two improvised explosives commonly used by terrorists in suicide attacks. This paper reports a relevant high-performance film-based fluorescent device, where a newly synthesized perylene monoimide modified non-planar organoboron derivative (PMI-BQ) was adopted as the sensing fluorophore. The performance of the device is excellent as evidenced by less than 2 s response time, no more than 10 s recovery time, nearly perfect reversibility, and lower than 50 ppm experimental detection limit (DL) for acetone. In addition, the presence of potential interferences showed little effect upon the sensing. Notably, more than 30 days sensing tests showed no observable degradation in the performance of the film device. Further tests revealed that the film-based device can be further used for the detection of TATP and DADP. The experimental DLs for the two explosives are lower than 30 and 50 μg, respectively. The superior performance of the device was ascribed to the non-planar structure of the sensing fluorophore as it may produce micro-channels in the film. Meanwhile, solvation may also play a crucial role in the process. We believe our contribution not only realizes reversible fluorescence sensing of acetone vapor and the related explosives, but also demonstrates that the combination of solvent effect and non-planar structure could be an effective way to develop high performance fluorescent sensing films. |
| Databáze: | OpenAIRE |
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