Photoinduced refractive-index change in 4-tert-butylcalix[8]arenes bearing N-acyloxyphenylamide chromophores

Autor:	Tetsutaro Igarashi, Tadamitsu Sakurai, Taichi Arai, Hiroya Suda
Rok vydání:	2012
Předmět:	Materials science Polymers and Plastics Chromophore Photochemistry law.invention Mercury-vapor lamp chemistry.chemical_compound Fragmentation (mass spectrometry) chemistry law Yield (chemistry) Calixarene Materials Chemistry Irradiation Refractive index Derivative (chemistry)
Zdroj:	Polymer Journal. 45:133-136
ISSN:	1349-0540 0032-3896
DOI:	10.1038/pj.2012.186
Popis:	When O-(4-acyloxyanilinocarbonylmethyl)-4-tert-butylcalix[8]arene films were irradiated for 60 min with 254-nm UV light from a low-pressure mercury lamp, the calixarene derivative 1 underwent a highly selective photo-Fries rearrangement in the film state to yield the corresponding Fries-rearranged product 2 along with a minor amount of the fragmentation product 3. This photochemical rearrangement enhanced the refractive index of the films by as much as 0.015.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::87bac87616e3f2920c7c13c03675b3a2 https://doi.org/10.1038/pj.2012.186 Zobrazit plný text záznamu