2-Carbamoylaziridine (Leakadine): diastereoselective transformations and stereoelectronic effect*
Autor: | I. I. Chervin, Remir G. Kostyanovsky, O. N. Krutius, G. K. Kadorkina |
---|---|
Rok vydání: | 2012 |
Předmět: | |
Zdroj: | Chemistry of Heterocyclic Compounds. 48:869-874 |
ISSN: | 1573-8353 0009-3122 |
Popis: | Diastereoselective transformations of Leakadine were discovered: dimerization during melting or heating in CHCl3 with the formation of one diastereomer. The obtained dimer reacts with methyl isocyanate under mild conditions with the formation of an N-methylcarbamoyl derivative – also in the form of one diastereomer. In the diastereoselective reaction of Leakadine with dimethyl formamide dimethyl acetal, 2-dimethylamino-1,3-diazabicyclo[3.1.0]hexan-4-one was obtained. The reaction of Leakadine with perfluoroisobutylene was studied. |
Databáze: | OpenAIRE |
Externí odkaz: |