Distance-Dependent para-H2→ortho-H2 Conversion in H2@C60 Derivatives Covalently Linked to a Nitroxide Radical

Autor:	Xuegong Lei, Yongjun Li, Ronald G. Lawler, Yasujiro Murata, Koichi Komatsu, Nicholas J. Turro
Rok vydání:	2011
Předmět:	Paramagnetism Nitroxide mediated radical polymerization Chemistry Stereochemistry Covalent bond Intramolecular force Polymer chemistry General Materials Science Physical and Theoretical Chemistry Nitroxide radical
Zdroj:	The Journal of Physical Chemistry Letters. 2:741-744
ISSN:	1948-7185
DOI:	10.1021/jz200192s
Popis:	The ortho-H2→para-H2 conversion in a series of H2@C60 derivatives covalently linked to a nitroxide radical has been investigated. The resulting conversion rates are in good agreement with the Wigner’s theory, modified for intramolecular interaction of H2 with the paramagnet.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::879df06c956792e5cf18bc3f882ea0c5 https://doi.org/10.1021/jz200192s Zobrazit plný text záznamu