Reactions of Aziridines with Ring Expansion

Autor:	A. P. Sineokov, F. N. Gladysheva, V. S. Etlis
Rok vydání:	1970
Předmět:	chemistry.chemical_compound Ethylene chemistry Intermolecular interaction Computational chemistry Intramolecular force Intermolecular force General Chemistry Ring (chemistry) Isomerization
Zdroj:	Russian Chemical Reviews. 39:118-129
ISSN:	1468-4837 0036-021X
DOI:	10.1070/rc1970v039n02abeh001943
Popis:	The review gives a systematic account of the literature on the reactions of aziridines with the expansion of the three-membered ring by intramolecular and intermolecular cyclisation mechanisms. The intermolecular interaction of aziridines with aldehydes and ketones, CO2, COS, and CS2, and with isocyanates and isothiocyanates with formation of five-membered heterocyclic compounds (oxazolidines, thiazolidinones, thiazolidinethiones, imidazolidinones, and others) is discussed. The isomerisation of N-vinyl and N-acyl derivatives to the corresponding pyrrolines, oxazolines, and other five-membered heterocyclic compounds as well as dimerisation reactions of aziridines and their interaction with epoxy ethylene and nitrones are discussed. The bibliography includes 88 references.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8787d5858171a1a22f9df9c1355a625d https://doi.org/10.1070/rc1970v039n02abeh001943 Zobrazit plný text záznamu