Use of carbon-13 nuclear magnetic resonance spectroscopy for determining the position of deuterium incorporation into simple alkenes and into tertiary phosphine complexes of platinum(II)

Autor: A. Derek H. Clague, Christopher Masters
Rok vydání: 1975
Předmět:
Zdroj: Journal of the Chemical Society, Dalton Transactions. :858
ISSN: 1364-5447
0300-9246
DOI: 10.1039/dt9750000858
Popis: Carbon-13 n.m.r. spectroscopy is shown to be a valuable analytical tool—offering considerable advantages over other physical methods—for investigating the site, and in some cases the degree, of deuterium incorporation in several simple alkenes and also in various tertiary phosphine complexes of platinum(II). 13C N.m.r. data are presented for the alkenes, CH2CHC(CH3)2R (R = Et, Pr, and Bu) together with their partially deuteriated analogues and also for the complexes [M2Cl4L2](M = Pd or Pt; and L = PEt3, PPr3, PBu3, or PBut2Pr) together with the partially deuteriated analogues [M = Pt and L = PPr3(D), PBu3(D), or PBut2Pr(D)].
Databáze: OpenAIRE