Structure of the intermediate iron(0) complex isolated from the dinitrogen fixing system LiPh + FeCl3

Autor:	Michel Gruselle, R.M. Lobkovskaya, G. Leny, A. K. Shilova, A.E. Shilov, T.A. Bazhenova, R.P. Shibaeva, B. Tchoubar
Rok vydání:	1983
Předmět:	Inorganic Chemistry Crystallography chemistry Organic Chemistry Atom Inorganic chemistry Materials Chemistry chemistry.chemical_element Physical and Theoretical Chemistry Biochemistry Carbon
Zdroj:	Journal of Organometallic Chemistry. 244:265-272
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)98618-2
Popis:	The structure of the complex Fe0(LiPh)4(Et2O)4, active towards dinitrogen, reveals a flat rectangular structure formed by carbon atoms of four phenyl rings linked by σ-bonds with Fe0 atom. The comparatively short interatomic distance between two carbon atoms of phenyl rings indicates some interaction between them. The possible mechanism of the reaction with N2 is considered.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::876e65309e58c12201ead2b06ff8f925 https://doi.org/10.1016/s0022-328x(00)98618-2 Zobrazit plný text záznamu