A 3D Nickel(II) Coordination Polymer with cds Nets Constructed from 3-Pyridin-4-yl-benzoic Acid
| Autor: | Feng Fu, Quirui Liu, Loujun Gao, Long Tang, Ya-Pan Wu, Xiaoming Gao |
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| Rok vydání: | 2011 |
| Předmět: |
chemistry.chemical_classification
Thermogravimetric analysis Coordination polymer Inorganic chemistry Infrared spectroscopy chemistry.chemical_element Crystal structure Coordination complex Inorganic Chemistry chemistry.chemical_compound Nickel chemistry Elemental analysis Polymer chemistry Benzoic acid |
| Zdroj: | Zeitschrift für anorganische und allgemeine Chemie. 637:608-612 |
| ISSN: | 0044-2313 |
| Popis: | A new coordination polymer, [Ni(3,4-pybz)2(H2O)]n (1), was hydrothermally synthesized from Ni(NO3)2·6H2O and an unsymmetrical 3-pyridin-4-yl-benzoic acid (3,4-Hpybz). It was characterized by IR spectroscopy, elemental analysis, thermogravimetric analysis, and single-crystal X-ray diffraction. In complex 1, the 3,4-pybz ligands act as linear linkers to join 4-connected nickel(II) ion nodes, to build a 3D 4-connected twofold interpenetrated 658-cds coordination framework. In addition, the magnetic and thermal properties of complex 1 were also investigated. |
| Databáze: | OpenAIRE |
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