Direct evidence for weak intramolecular O–H⋯π hydrogen bonding in 1-hydroxytetralin

Autor:	Yu-ichiro Tsutsumi, Tasuku Isozaki, Tadashi Suzuki, Teijiro Ichimura
Rok vydání:	2010
Předmět:	Hydrogen Hydrogen bond General Physics and Astronomy chemistry.chemical_element Ring (chemistry) Photochemistry Spectral line chemistry.chemical_compound chemistry Intramolecular force Physical and Theoretical Chemistry Benzene Conformational isomerism Excitation
Zdroj:	Chemical Physics Letters. 495:175-178
ISSN:	0009-2614
DOI:	10.1016/j.cplett.2010.06.081
Popis:	Laser-induced fluorescence (LIF) excitation and single vibronic level fluorescence (SVLF) spectra of jet-cooled 1-hydroxytetralin (1HT) have been measured to investigate the nature of weak intramolecular hydrogen bonding. The vibronic bands observed in the LIF excitation spectrum were responsible for two conformers resulting from different configurations of the saturated six-membered ring with the orientation of the hydroxyl group. The hydroxyl hydrogen in the stable conformers was directed toward the benzene π-electrons. The conformational preferences in 1HT clearly indicate the weak intramolecular O–H ⋯ π hydrogen bonding.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8748d82bf562664ab61e54282271c815 https://doi.org/10.1016/j.cplett.2010.06.081 Zobrazit plný text záznamu Full Text from ScienceDirect