An improved NMR spin-echo apparatus for the measurement of self-diffusion coefficients: The diffusion of water in aqueous electrolyte solutions

Autor: D.S Webster, R Mills, Phillip J. Back, Kenneth R. Harris
Rok vydání: 1978
Předmět:
Zdroj: Journal of Magnetic Resonance (1969). 29:473-482
ISSN: 0022-2364
DOI: 10.1016/0022-2364(78)90005-7
Popis: An NMR spin-echo apparatus for the measurement of self-diffusion by the steady-gradient technique is described. Particular attention was paid to reducing errors. A reproducibility of ±1% was obtained and the overall accuracy is estimated as ±2%. Data for the self-diffusion coefficients of water in aqueous NaCl, NaI, KI, and MgCl2 solutions at 10 and 25°C and in aqueous BaCl2 solutions at 25°C are reported.
Databáze: OpenAIRE