Evaluation of the Inhibition Efficiency of a Green Inhibitor on Corrosion of Cu-Ni Alloys in the Marine Application
| Autor: | Maamoun A. Maamoun, Wafaa A. Ghanem, Ghalia A. Gaber |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Chemistry
Mechanical Engineering Metallurgy technology industry and agriculture 02 engineering and technology equipment and supplies 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Corrosion Mechanics of Materials General Materials Science 0210 nano-technology |
| Zdroj: | Key Engineering Materials. 786:174-194 |
| ISSN: | 1662-9795 |
| Popis: | The aim of this article describes the application of green tea aqueous extract as an eco-friendly corrosion inhibitor for two Cu-Ni alloys in 3.5% NaCl solution. This ability has been studied by using electrochemical techniques (i.e. PDP, CT and EIS), IR spectroscopy measurements and the surface analysis technique (i.e. SEM/EDX). This ability was compared with it's of a commercial cooling water (green water). The results show that tested extract exhibited a good ability to decrease the corrosion rate of alloys in 3.5% NaCl solution.The inhibition efficiency of the green water and green tea extract inhibitors increased with increasing the concentration and decreased with increasing the temperature. The inhibition efficiency of two Cu-Ni alloys which reaching ̴ 91.5% and ̴ 93.9% with 50 % green tea aqueous extract for Cu-10 Ni and Cu-30 Ni alloy, respectively. Electrochemical impedance showed that the change in charge transfer resistance (Rct) and double layer capacity (Cdl) which adsorbed on the alloy surface. Adsorption of the inhibitors gives a good fit to Langmuir isotherm model. Some thermodynamic parameters of activation and adsorption processes were also determined and discussed. Surface examination studies by SEM and EDX confirm the presence of protective film on the alloy surface. In the present study, we investigated the corrosion of the Cu-Ni (cupronickel) alloys in 3.5 % NaCl environment to simulate the seawater desalination plants conditions. Therefore, the future studies can be focused on the development of polymeric compounds used as self- healing or production of new natural corrosion inhibitors especially recommended the waste product of green tea. |
| Databáze: | OpenAIRE |
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