Rhodium(II) (S)-N-(arylsulfonyl)prolinate catalyzed asymmetric insertions of vinyl- and phenylcarbenoids into the SiH bond

Autor:	James Rutberg, Huw M. L. Davies, Paul R. Bruzinski, Tore Hansen
Rok vydání:	1997
Předmět:	Sulfonyl chemistry.chemical_classification chemistry Organic Chemistry Drug Discovery chemistry.chemical_element Enantiomer Biochemistry Decomposition Medicinal chemistry Catalysis Rhodium
Zdroj:	Tetrahedron Letters. 38:1741-1744
ISSN:	0040-4039
Popis:	Allylsilanes or benzylsilanes of high enantiomeric purity (77–95% ee) are formed from the rhodium(II) (S)-N-[p-(dodecylphenyl)sulfonyl]prolinate ( 1 ) catalyzed decomposition of vinyldiazomethanes or phenyldiazomethanes in the presence of dimethylphenylsilane ( 3 ).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::870a18b3e0d71b449a5252a8e3813dab https://doi.org/10.1016/s0040-4039(97)00205-0 Zobrazit plný text záznamu Full Text from ScienceDirect