Thermally stable La-Ni-B amorphous additives for enhancing hydrogen storage performance of MgH2
Autor: | Zhou Peng Li, Zi Jun Gao, Bin Hong Liu |
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Rok vydání: | 2021 |
Předmět: |
Materials science
Hydrogen Mechanical Engineering Metals and Alloys chemistry.chemical_element Amorphous solid law.invention Catalysis Hydrogen storage chemistry Chemical engineering X-ray photoelectron spectroscopy Mechanics of Materials law Materials Chemistry Dehydrogenation Crystallization High-resolution transmission electron microscopy |
Zdroj: | Journal of Alloys and Compounds. 888:161520 |
ISSN: | 0925-8388 |
DOI: | 10.1016/j.jallcom.2021.161520 |
Popis: | In this work, we synthesized La-incorporated Ni-B amorphous composites and investigated their effects on enhancing dehydrogenation/hydrogenation properties of MgH2. MgH2 with 5 wt% 2La-3Ni-B demonstrated significantly improved dehydriding kinetics. About 6.0 wt% hydrogen could be released within 5 min at 300 °C. Moreover, no decrease in deydrogenation rate was observed within ten cycles. XRD, XPS, SEM and HRTEM examinations revealed that the La incorporation into Ni-B resulted in an amorphous La-B-O structure that could keep its disorder state up to 600 °C. The crystallization and growth of Ni dispersed in the La-B-O structure was significantly retarded. Also the alloying of Mg with Ni or La was not observed. As a result, the added La-Ni-B composites showed higher structural and catalytic stability than Ni-B during hydriding/dehydriding cycling of MgH2 at high temperatures. |
Databáze: | OpenAIRE |
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