A nuclear magnetic resonance study of pyramidal atomic inversion in complexes of tricarbonylrhenium(I) halides with saturated and unsaturated thio- and seleno-ethers: an X-ray crystal structure of [Rel(CO)3{MeSe(CH2)2SeMe}]

Autor:	Suresh K. Bhargava, Mohamed A. Mazid, Keith G. Orrell, Vladimir Šik, Michael B. Hursthouse, B. L. Williams, Kenneth Kite, K. M. Abdul Malik, Maqbool M. Bhatti, Edward W. Abel
Rok vydání:	1982
Předmět:	Ring size Chalcogen Nuclear magnetic resonance Chemistry Halogen X-ray Halide Thio General Chemistry Crystal structure
Zdroj:	J. Chem. Soc., Dalton Trans.. :2065-2072
ISSN:	1364-5447 0300-9246
DOI:	10.1039/dt9820002065
Popis:	Complexes of the type [ReX(CO)3L][X = Cl, Br, or I; L = MeE(CH2)nEMe (n= 2 or 3, E = S or Se) or MeECHCHEMe (E = S or Se)] have been prepared and the energy barriers associated with the pyramidal inversions at individual chalcogen atoms calculated using total bandshape dynamic n.m.r. methods. The effects of ring size, conjugation, and the nature of the halogen on barrier energies are discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::86f7fb19bf5a2a6e6b4279ffdc114fd2 https://doi.org/10.1039/dt9820002065 Zobrazit plný text záznamu