Hydrogenation catalysts: A synthetic hydrogenase model

Autor:	Gisela Henrici-Olivé, Salvador Olivé
Rok vydání:	1976
Předmět:	Nickel Chelating ligands Hydrogenase Chemistry Hydrogen molecule Kinetic analysis General Engineering chemistry.chemical_element Organic chemistry Combinatorial chemistry Catalysis Palladium
Zdroj:	Journal of Molecular Catalysis. 1:121-135
ISSN:	0304-5102
DOI:	10.1016/0304-5102(76)80006-5
Popis:	A series of complexes of Group VIII metals with square-planar chelating ligands has been prepared. Nickel(II) and palladium(II) complexes can easily be isolated in a pure state. Some of these complexes, especially PdII-SALEN, activate molecular hydrogen thus catalyzing HD exchange and the hydrogenation of olefins. A kinetic analysis shows a very close analogy in behaviour with that of hydrogenase. A mechanism for exchange and hydrogenation is suggested. Possible consequences for other transition-metal-containing enzymes are discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::86f65d2a841f366daac913f2b1dd1bc3 https://doi.org/10.1016/0304-5102(76)80006-5 Zobrazit plný text záznamu