ChemInform Abstract: 9-Methyl-9-nitro-10-nitromethylene-9,10-dihydroanthracene. The First Isolation of a Proposed Intermediate for the Side-Chain Nitration of Arenes Under Heterolytic Conditions

Autor:	Toshimi Katayama, Hitomi Suzuki, Emiko Kimura, Takuji Ogawa
Rok vydání:	1987
Předmět:	chemistry.chemical_compound Anthracene chemistry Nitric acid Nitration Nitro General Medicine DABCO 9 10-Dihydroanthracene Medicinal chemistry Heterolysis Dichloromethane
Zdroj:	ChemInform. 18
ISSN:	0931-7597
DOI:	10.1002/chin.198750169
Popis:	Reaction of 9-methy 1-10-nitromethylanthracene with nitric acid in dichloromethane at low temperatures followed by treatment with DABCO gave 9,10-bis(nitromethy1(anthracene and the title compound. The latter is converted by further action of nitric acid to 9-methy1-10-trinitromethylanthracene, 10-methyl-9-anthrylnitrile oxide, and other oxidation products.
Databáze:	OpenAIRE
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