Oxidations involving phosphate species supported on TS-1: a novel class of grafted catalysts

Autor:	E. Duprey, Jean-Marie Brégeault, M. Delamar, J. Maquet, P.P. Man, J.-M. Manoli
Rok vydání:	1995
Předmět:	Aqueous solution Denticity Process Chemistry and Technology fungi Inorganic chemistry food and beverages Heterogeneous catalysis Phosphate Molecular sieve Catalysis chemistry.chemical_compound chemistry Polymer chemistry Chelation Hydrogen peroxide
Zdroj:	Applied Catalysis A: General. 128:89-96
ISSN:	0926-860X
DOI:	10.1016/0926-860x(95)00078-x
Popis:	Phosphate species deposited on titanium silicalite (TS-1) can interfere with epoxidation by hydrogen peroxide. Phosphates grafted on TS-1 are identified by solid-state31P MAS NMR. Signals at −5.1, −10.8 and −20 ppm are attributed to monodentate, chelating or bridging phosphate ions and polyphosphates, respectively. Phosphate-modified TS-1 can anchor tungsten oxoperoxo species; with aqueous hydrogen peroxide, this novel class of supported catalysts can oxidize bulky molecules under mild conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::86ad241555e97972bd67090b4a282b61 https://doi.org/10.1016/0926-860x(95)00078-x Zobrazit plný text záznamu Full Text from ScienceDirect