ESR study of the interaction of mononuclear and binuclear metal carbonyls with silicon hydrides and the use of these systems to generate ?-chlorine-containing radicals

Autor:	R. G. Gasanov, R. Kh. Freidlina
Rok vydání:	1981
Předmět:	chemistry Silicon Radical Spin trap Chlorine chemistry.chemical_element Metal carbonyl General Chemistry Photochemistry
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 30:980-984
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00950276
Popis:	1. As a result of the interaction of mononuclear metal carbonyls M(CO)n (M=Cr, Fe, Mo, W) and binuclear metal carbonyls M2(CO)10 (M=Mn, Re) with (C2H5)3SiH and C2H5SiCl2H, the radicals (C2H5)3Si, (C2H5)329Si, (C2H5)SiCl2, and (C2H5)29SiCl2 are formed; these radicals have been detected and identified by ESR, using 2,4,6-tri-tert-butylnitrosobenzene as a spin trap. 2. The reaction of a system consisting of a metal carbonyl and (C2H5)3SiH with gempolychlorinated compounds effectively generates α-chlorine-containing radicals.
Databáze:	OpenAIRE
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