Physicochemical and catalytic characteristics of La-H-ZSM-5 zeolite in converting dimethyl ether to the mixtures of gasoline hydrocarbons: Effect of ion exchange conditions

Autor: Z. M. Bukina, D. A. Ionin, V. V. Yushchenko, L. E. Kitaev, N. V. Kolesnichenko, S. N. Khadzhiev
Rok vydání: 2014
Předmět:
Zdroj: Russian Journal of Physical Chemistry A. 88:381-385
ISSN: 1531-863X
0036-0244
Popis: The effect of the manner and conditions of introducing lanthanum cations into NH4-ZSM-5 zeolite on the properties of catalysts for the conversion of dimethyl ether into the mixtures of gasoline hydrocarbons is studied. The physicochemical properties of synthesized catalysts are studied by means of temperature-programmed ammonia desorption, the adsorption of benzene, atomic absorption spectroscopy, differential scanning calorimetry, and thermogravimetry. It is shown that the degree to which lanthanum cations are replaced by ammonium cations both depends on the conditions of ion exchange in the zeolite and affects its acidity spectrum and the selectivity of the formation of paraffin hydrocarbons with isostructure. It is concluded that an increase in the amount of introduced lanthanum leads to an increase in the content of iso-paraffins from 69 to 76 wt % and a decrease in the content of aromatic hydrocarbons from 10.5 to 5.5 wt % and that of durene from 1.5 to 0.2 wt % in the products.
Databáze: OpenAIRE
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