Encagement of Gold Nanoclusters in Crosslinked Resorcinarene Shells

Autor:	Kevin B. Stavens, Stephen V. Pusztay, Ronald P. Andres, Alexander Wei
Rok vydání:	2002
Předmět:	Gel permeation chromatography Reaction rate constant Chemistry Monolayer Calixarene Polymer chemistry Proton NMR Nanoparticle General Chemistry Resorcinarene Nanoclusters
Zdroj:	Supramolecular Chemistry. 14:291-294
ISSN:	1029-0478 1061-0278
DOI:	10.1080/10610270290026202
Popis:	Monolayers of resorcinarene tetraene 1 on gold nanoclusters could be crosslinked by olefin metathesis into a nondesorptive shell. Crosslinking conditions were optimized by monitoring olefin metathesis of 1 by 1 H NMR spectroscopy and obtaining empirical rate constants. Gel permeation chromatography (GPC) was found to be a useful tool for evaluating the enhanced stability of the encaged nanoparticles; resorcinarene-encapsulated nanoparticles which were not subjected to olefin metathesis did not survive GPC analysis, whereas nanoparticles in crosslinked shells were found to be stable.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::86743d6bf32e253959d0aa712a1c07db https://doi.org/10.1080/10610270290026202 Zobrazit plný text záznamu Plný text ve formátu PDF